An efficient biomimetic Fe-catalyzed epoxidation of olefins using hydrogen peroxide.
نویسندگان
چکیده
A new, environmentally benign and practical epoxidation method was developed using inexpensive and efficient Fe catalysts. FeCl3.6H2O in combination with commercially available pyridine-2,6-dicarboxylic acid and amines showed excellent reactivity and selectivity towards aromatic olefins and moderate reactivity towards 1,3-cyclooctadiene utilizing H2O2 as the terminal oxidant.
منابع مشابه
Epoxidation of Alkenes and Oxidation of Alcohols with Hydrogen Peroxide Catalyzed by a Fe (Br8TPPS) Supported on Amberlite IRA-400
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عنوان ژورنال:
- Chemical communications
دوره 3 شماره
صفحات -
تاریخ انتشار 2007